Benzaldehyde → HCID 10997368, compound

Participants

Reaction Conditions

Reaction Steps

0.4 g (0.64 mmol) of the titanium compound prepared as in Example 4 are dissolved in 40 ml of diethyl ether, the solution is cooled to -74° C., 0.065 ml (0.65 mmol) of benzaldehyde are added and the mixture is stirred for 2 hours at -74° C. The reaction solution is then solution is then hydrolysed with 20 ml of aqueous ammonium fluoride solution, stirred overnight at RT, filtered through Hyflo and extracted with 3×40 ml of diethyl ether and the extract is washed with saturated NaCl solution, dried over Na2SO4 and evaporated.

Provenance & Evidence