N-Methylbutylamine → HCID 54165061, compound

HRID 728577Notes

Reaction equation

HRID 728577 reaction equation
[N+:1]([CH:4]=[C:5](SC)[S:6][CH3:7])([O-:3])=[O:2].[CH2:10]([NH:14][CH3:15])[CH2:11][CH2:12][CH3:13]>C1(C)C=CC=CC=1>[CH2:10]([N:14]([C:5]([S:6][CH3:7])=[CH:4][N+:1]([O-:3])=[O:2])[CH3:15])[CH2:11][CH2:12][CH3:13]

Participants

4

Reactant 2

HCID 8068N-MethylbutylamineHCID 836231,1-Bis(methylthio)-2-nitroethylene

Product 1

HCID 54165061HCID 54165061, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

A solution of 8.26 g (0.05 mol) of 1-nitro-2,2-di(methylthio)ethylene and 5.25 g (0.06 mol) of N-n-butyl-N-methylamine in toluene is refluxed for 2 hours. After evaporation of the toluene under vacuum, 10.2 g of 2-(N-butyl-N-methylamino)-2-methylthio-1-nitroethylene are isolated as an oil (nD21 =1.584). (Compound 2.1, Table 2).

Workup

  1. customAfter evaporation of the toluene under vacuum, 10.2 g of 2-(N-butyl-N-methylamino)-2-methylthio-1-nitroethylene
  2. customare isolated as an oil (nD21 =1.584)

Sources & evidence

ORD record
ord-fd3bc811432a448ea31989fc409fd280
Source dataset
uspto-grants-1991_09
Patent number
US05049571

Reaction notes

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