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HRID728755

反应详情

EQUATION

反应方程式

HRID 728755 的结构方程式

REACTANTS

反应物

2
结构：c1cc[nH]c1
HCID8027

Pyrrole

C4H5N

结构：O=Cc1ccc(C(=O)O)cc1
HCID12088

4-Carboxybenzaldehyde

C8H6O3

PRODUCTS

生成物

1
结构：O=C(O)c1ccc(-c2c3nc(c(-c4ccc(C(=O)O)cc4)c4ccc([nH]4)c(-c4ccc(C(=O)O)cc4)c4nc(c(-c5ccc(C(=O)O)cc5)c5ccc2[nH]5)C=C4)C=C3)cc1
HCID86278368

4,4',4'',4'''-(5,10,15,20-Porphyrintetrayl)tetrabenzoic acid

C48H30N4O8

收率 17.5%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCC(=O)O
溶剂HCID1032

未命名化合物

PROCEDURE

实验过程

In refluxed propionic acid, 30 g of 4-carboxybenzaldehyde was reacted with 13.4 g of pyrrole to obtain 6.9 g of 5,10,15,20-tetra(4-carboxyphenyl)porphine. This porphine derivative was reacted with an aqueous solution containing four equivalents of sodium hydroxide to obtain tetrasodium 5,10,15,20-tetra(4-carbonatophenyl)porphine.