Cyclohexanecarboxylic acid → HCID 86620827, compound

HRID 732331Notes

Reaction equation

[C:1](=[O:13])([S:11][CH3:12])[O:2][CH:3]([O:5][C:6](=[O:10])[CH:7]([CH3:9])[CH3:8])C.ClC(OCCl)=O.[CH:20]1(C(O)=O)[CH2:25]CCC[CH2:21]1>>[C:1](=[O:13])([S:11][CH3:12])[O:2][CH2:3][O:5][C:6]([CH:7]1[CH2:9][CH2:25][CH2:20][CH2:21][CH2:8]1)=[O:10]

Participants

Reactant 3

HCID 7413Cyclohexanecarboxylic acid

HCID 62754Chloromethyl chloroformate

HCID 577926891-[[(Methylthio)carbonyl]oxy]ethyl 2-methylpropanoate

Product 1

HCID 86620827HCID 86620827, compound

Procedure

Following the procedures for synthesizing O-(1-isobutanoyloxyethyl) S-methyl thiocarbonate (2) and replacing 1-chloroethyl chloroformate with chloromethyl chloroformate in Step A and replacing isobutyric acid with cyclohexanecarboxylic acid in Step B affords O-(cyclohexanoyloxymethyl) S-methyl thiocarbonate (10) as an oil.

Sources & evidence

ORD record: ord-05f9ebc57d4f474ba8694d41011c6af9
Source dataset: uspto-grants-2009_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07585996B2

Reaction notes

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