4-Hydroxybenzaldehyde → 3-(4-Formylphenoxy)-2-hydroxypropyl 2-methylprop-2-enoate

HRID 732844Notes

Reaction equation

HRID 732844 reaction equation
[C:1]([O:6][CH2:7][CH:8]1[O:10][CH2:9]1)(=[O:5])[C:2]([CH3:4])=[CH2:3].[OH:11][C:12]1[CH:19]=[CH:18][C:15]([CH:16]=[O:17])=[CH:14][CH:13]=1.[NH4+].N(N(C1C=CC=CC=1)O)=O>N1C=CC=CC=1>[C:1]([O:6][CH2:7][CH:8]([OH:10])[CH2:9][O:11][C:12]1[CH:19]=[CH:18][C:15]([CH:16]=[O:17])=[CH:14][CH:13]=1)(=[O:5])[C:2]([CH3:4])=[CH2:3]

Participants

5

Reactant 3

HCID 1264-HydroxybenzaldehydeHCID 7837Glycidyl methacrylateHCID 178526394HCID 178526394, compound

Product 1

HCID 231378123-(4-Formylphenoxy)-2-hydroxypropyl 2-methylprop-2-enoate

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Conditions

Temperature
80 °C

Procedure

Into a reaction vessel were placed 56 g of glycidyl methacrylate, 48 g of p-hydroxybenzaldehyde, 2 g of pyridine and 1 g of N-nitroso-phenylhydroxylamine ammonium salt and reacted with stirring in a water bath at 80° C. for 8 hrs to obtain p-(3-methacryloxy-2-hydroxypropyloxy)benzaldehyde.

Workup

  1. customInto a reaction vessel were placed

Sources & evidence

ORD record
ord-083055318cd4489e97dc0cb20e330830
Source dataset
uspto-grants-2009_09
Patent number
US07588330B2

Reaction notes

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