Ethyl Acetate → HCID 4643227, compound

HRID 734808Notes

Reaction equation

HRID 734808 reaction equation
[Br:1][C:2]1[CH:3]=[CH:4][C:5]([OH:11])=[C:6]([C:8](=[O:10])[CH3:9])[CH:7]=1.[CH3:12][CH2:13][O:14]C(C)=O>>[Br:1][C:2]1[CH:3]=[CH:4][C:5]([O:11][CH2:12][CH2:13][OH:14])=[C:6]([C:8](=[O:10])[CH3:9])[CH:7]=1

Participants

3

Reactant 2

HCID 8857Ethyl AcetateHCID 959915'-Bromo-2'-hydroxyacetophenone

Product 1

HCID 4643227HCID 4643227, compound

Procedure

The product was prepared analogously to Example 1.1a starting from 1-(5-bromo-2-hydroxyphenyl)ethanone. Yield: 7.30 g (30% of theoretical); C10H11BrO3 (M=259.097); calc.: molpeak (M+H)+: 259/261 (Br); found: molpeak (M+H)+: 259/261 (Br); Rf value: 0.25 (silica gel, PE/EtOAc 1:1).

Workup

  1. customThe product was prepared analogously to Example 1.1a

Sources & evidence

ORD record
ord-a0c43c6b3b1844b8943f4023563be8ab
Source dataset
uspto-grants-2009_09
Patent number
US07592358B2

Reaction notes

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