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HRID735087

反应详情

EQUATION

反应方程式

HRID 735087 的结构方程式

REACTANTS

反应物

2
结构：O=C=O
HCID280

Carbon dioxide

CO2

结构：Clc1cc(Cl)c(C#C[Si](c2ccccc2)(c2ccccc2)c2ccccc2)c(Cl)c1
HCID86060684

1,3,5-Trichloro-2-[2-(triphenylsilyl)ethynyl]benzene

C26H17Cl3Si

PRODUCTS

生成物

1
结构：O=C(O)C#Cc1c(Cl)cc(Cl)cc1Cl
HCID68816017

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(=O)O.CO.ClCCl
溶剂HCID21877243

未命名化合物

PROCEDURE

实验过程

Prepared analogously to Example 4.3.a. from triphenyl-(2,4,6-trichlorophenylethynyl)silane and dry ice. Yield: 3.3 g (77.7% of theory); melting point: 170° C.-175° C.; C9H3Cl3O2 (M=249.48); calc.: molecular ion peak (M+H)+: 249/251/253; found: molecular ion peak (M+H)+: 249/251/253; Rf value: 0.4 (silica gel, dichloromethane/methanol/acetic acid (50:10:1)).

WORKUP

后处理

  1. customPrepared analogously to Example 4.3.a