HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Dioxide → (2,4,6-trichlorophenyl)propynoic Acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Dioxide | HCID 280 | — |
| Reactant | Triphenyl-(2,4,6-trichlorophenylethynyl)silane | HCID 86060684 | — |
| Solvent | DCM MeOH AcOH | HCID 21877243 | — |
| Product | (2,4,6-trichlorophenyl)propynoic Acid | HCID 68816017 | — |
Reaction Steps
Prepared analogously to Example 4.3.a. from triphenyl-(2,4,6-trichlorophenylethynyl)silane and dry ice. Yield: 3.3 g (77.7% of theory); melting point: 170° C.-175° C.; C9H3Cl3O2 (M=249.48); calc.: molecular ion peak (M+H)+: 249/251/253; found: molecular ion peak (M+H)+: 249/251/253; Rf value: 0.4 (silica gel, dichloromethane/methanol/acetic acid (50:10:1)).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07592373B2 |
| Source dataset | uspto-grants-2009_09 |
| ORD ID | ord-0748d7ca0dc54f9f8fa910991e7e2828 |
| Source note | uspto-grants-2009_09 |