Lithium hydroxide, monohydrate → HCID 86601151, compound

HRID 735386Notes

Reaction equation

HRID 735386 reaction equation
[CH3:1][C:2]1([CH3:33])[C:11]2[CH:10]=[C:9]([Se:12][C:13]3[CH:14]=[C:15](/[CH:19]=[CH:20]/[C:21]([O:23]CC)=[O:22])[CH:16]=[CH:17][CH:18]=3)[CH:8]=[CH:7][C:6]=2[C:5]([C:26]2[CH:31]=[CH:30][C:29]([CH3:32])=[CH:28][CH:27]=2)=[CH:4][CH2:3]1.O.[OH-].[Li+]>>[CH3:1][C:2]1([CH3:33])[C:11]2[CH:10]=[C:9]([Se:12][C:13]3[CH:14]=[C:15](/[CH:19]=[CH:20]\[C:21]([OH:23])=[O:22])[CH:16]=[CH:17][CH:18]=3)[CH:8]=[CH:7][C:6]=2[C:5]([C:26]2[CH:27]=[CH:28][C:29]([CH3:32])=[CH:30][CH:31]=2)=[CH:4][CH2:3]1

Participants

3

Reactant 2

HCID 168937Lithium hydroxide, monohydrateHCID 86601152HCID 86601152, compound

Product 1

HCID 86601151HCID 86601151, compound

Procedure

In a manner similar to that of Example 1g, by reacting 0.088 g (0.18 mmol) of ethyl (E)-3-[3-(8,8-dimethyl-5-p-tolyl-7,8-dihydro-2-naphthylselanyl)phenyl]acrylate with 0.09 g (2.14 mmol) of lithium hydroxide hydrate, a yellow solid is obtained (0.06 g; yield=73%).

Workup

  1. customa yellow solid is obtained (0.06 g; yield=73%)

Sources & evidence

ORD record
ord-bf04d176bc2143d8a4896fe168fa7b8b
Source dataset
uspto-grants-2009_09
Patent number
US07592478B2

Reaction notes

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