1,3-Butadiene → HCID 13623398, compound

HRID 735400Notes

Reaction equation

HRID 735400 reaction equation
[CH3:1][C:2]1[C:3](=[O:9])[CH2:4][CH2:5][CH:6]([CH3:8])[CH:7]=1.[CH2:10]=[CH:11][CH:12]=C.[Cl-].[Cl-].[CH2:16]([Al+2])C>ClCCl>[CH3:8][CH:6]1[CH:7]2[C:2]([CH3:16])([CH2:1][CH:10]=[CH:11][CH2:12]2)[C:3](=[O:9])[CH2:4][CH2:5]1

Participants

5

Reactant 3

HCID 78451,3-ButadieneHCID 131494292,4-Dimethylcyclohex-2-en-1-oneHCID 16686341Ethyl aluminium dichloride

Product 1

HCID 13623398HCID 13623398, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2,4-Dimethyl-2-cyclohexen-1-one (10.0 g, 0.081 mol), Butadiene (8.75 g, 0.162 mol), Ethyl aluminium dichloride (1 molar solution in hexane, 40 ml, 0.040 mol), Dichloromethane (100 ml)

Sources & evidence

ORD record
ord-726f0547c53d4324ac1124cb481e63ab
Source dataset
uspto-grants-2009_09
Patent number
US07592492B2

Reaction notes

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