HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Butadiene → 4,8a-Dimethyl-3,4,4a,5,8,8a-hexahydro-1(2H)-naphthalenone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Butadiene | HCID 7845 | — |
| Reactant | 2,4-Dimethylcyclohex-2-en-1-one | HCID 13149429 | — |
| Reactant | Ethyl aluminium dichloride | HCID 16686341 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 4,8a-Dimethyl-3,4,4a,5,8,8a-hexahydro-1(2H)-naphthalenone | HCID 13623398 | — |
Reaction Steps
2,4-Dimethyl-2-cyclohexen-1-one (10.0 g, 0.081 mol), Butadiene (8.75 g, 0.162 mol), Ethyl aluminium dichloride (1 molar solution in hexane, 40 ml, 0.040 mol), Dichloromethane (100 ml)
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07592492B2 |
| Source dataset | uspto-grants-2009_09 |
| ORD ID | ord-726f0547c53d4324ac1124cb481e63ab |
| Source note | uspto-grants-2009_09 |