1,3-Butadiene → HCID 68816620, compound

HRID 735401Notes

Reaction equation

HRID 735401 reaction equation
[CH2:1]([CH:3]1[CH2:8][CH2:7][C:6](=[O:9])[C:5]([CH3:10])=[CH:4]1)[CH3:2].[CH2:11]=[CH:12][CH:13]=C.[Cl-].[Cl-].[CH2:17]([Al+2])C>ClCCl>[CH2:1]([CH:3]1[CH:4]2[C:5]([CH3:17])([CH2:10][CH:11]=[CH:12][CH2:13]2)[C:6](=[O:9])[CH2:7][CH2:8]1)[CH3:2]

Participants

5

Reactant 3

HCID 78451,3-ButadieneHCID 16686341Ethyl aluminium dichlorideHCID 23103012HCID 23103012, compound

Product 1

HCID 68816620HCID 68816620, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Prepared according to the general procedure # I, with the following quantities: 4-Ethyl-2-methyl-2-cyclohexen-1-one (27.6 g, 0.20 mol), Butadiene (21.6 g, 0.040 mol), Ethyl aluminium dichloride (1 molar solution in hexane, 100 ml, 0.10 mol), Dichloromethane (300 ml)

Workup

  1. customPrepared

Sources & evidence

ORD record
ord-012df96005084fa0a7dd3f88c28e9755
Source dataset
uspto-grants-2009_09
Patent number
US07592492B2

Reaction notes

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