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HRID735511

反应详情

EQUATION

反应方程式

HRID 735511 的结构方程式

REACTANTS

反应物

4
结构：CC(C)(C)S
HCID6387

tert-Butyl mercaptan

C4H10S

结构：O=C(OO)c1cccc(Cl)c1
HCID70297

Benzenecarboperoxoic acid, 3-chloro-

C7H5ClO3

结构：N#Cc1cc([N+](=O)[O-])ccc1F
HCID519417

2-Fluoro-5-nitrobenzonitrile

C7H3FN2O2

结构：CCS(=O)(=O)c1ccc([N+](=O)[O-])cc1C#N
HCID57448182

2-(Ethanesulfonyl)-5-nitrobenzonitrile

C9H8N2O4S

PRODUCTS

生成物

1
结构：CC(C)(C)S(=O)(=O)c1ccc([N+](=O)[O-])cc1C#N
HCID57842722

未命名化合物

收率 88%

PROCEDURE

实验过程

Using a procedure analogous to that used to prepare 6A, 2-fluoro-5-nitrobenzonitrile (2.50 g, 15.6 mmol) was reacted with tert-butylthiol and oxidized with mCPBA to afford 10A (3.14 g, 88%) as a white solid. 1H NMR (400 MHz, CDCl3) δ 1.45 (s, 9 H), 7.88 (d, J=8.79 Hz, 1 H), 8.37 (dd, J=8.35, 2.64 Hz, 1 H), 8.55 (d, J=2.64 Hz, 1 H).