HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,2'-Bipyridine → 1,3,5-Trifluorobenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,2'-Bipyridine | HCID 1474 | — |
| Reactant | 1,3,5-Trichloro-2,4,6-trifluorobenzene | HCID 67573 | — |
| Catalyst | Zinc | HCID 23994 | — |
| Catalyst | Nickel Dichloride | HCID 24385 | — |
| Product | 1,3,5-Trifluorobenzene | HCID 9745 | — |
Reaction Steps
In Russ. J. of Org. Chem., vol. 36, 1, pp. 132-33 (2000) describes the dehalogenation of 1,3,5-trichlorotrifluorobenzene by means of zinc in the presence of NiCl2 and bipyridine to give 1,3,5-trifluorobenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07595426B2 |
| Source dataset | uspto-grants-2009_09 |
| ORD ID | ord-b80bfc5beb70417dbc87902599aa7ed0 |
| Source note | uspto-grants-2009_09 |