1-Bromo-3-chloropropane → HCID 86762708, compound

HRID 74323Notes

Reaction equation

HRID 74323 reaction equation
[Cl:1][CH2:2][CH2:3]/[CH:4]=[CH:5]\[CH2:6][CH2:7]/[CH:8]=[CH:9]\[CH:10]=[CH:11]\[CH2:12][CH3:13].Br[CH2:15][CH2:16][CH2:17]Cl>>[Cl:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6]/[CH:7]=[CH:8]\[CH2:9][CH2:10]/[CH:11]=[CH:12]\[CH:13]=[CH:15]\[CH2:16][CH3:17]

Participants

3

Reactant 2

HCID 80061-Bromo-3-chloropropaneHCID 86762710HCID 86762710, compound

Product 1

HCID 86762708HCID 86762708, compound

Procedure

The (Z,Z,E)-1-chloro-3,7,9-dodecatriene (2) is converted into a corresponding Grignard reagent and then the Grignard reagent is reacted with 1-bromo-3-chloropropane to obtain (Z,Z,E)-1-chloro-6,10,12-pentadecatriene (3).

Sources & evidence

ORD record
ord-b097e6599cc14984823b35f084588773
Source dataset
uspto-grants-2014_09
Patent number
US08829255B1

Reaction notes

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