Isopropyl chloroformate → Methylenechloride Hexane

HRID 744697Notes

Reaction equation

HRID 744697 reaction equation
[Cl:1][C:2](O[CH:5]([CH3:7])[CH3:6])=O.[C:8]([Cl:14])(=O)[CH2:9][CH:10](C)C>>[CH3:6][CH2:5][CH2:7][CH2:8][CH2:9][CH3:10].[Cl:14][CH2:2][Cl:1]

Participants

3

Reactant 2

HCID 7917Isopropyl chloroformateHCID 66054Isovaleryl chloride

Product 1

HCID 21226440Methylenechloride HexaneYield 87%

Procedure

This compound was prepared according to the method described in Example 7, except that isopropyl chloroformate was replaced by an equivalent portion of isovaleryl chloride. The product was purified by recrystallization from a mixture of hexane/dichloromethane as colourless crystals mp 97°-80° C., yield 87%.

Workup

  1. customThis compound was prepared

Sources & evidence

ORD record
ord-a0d03c1e0287463995d930e90d703661
Source dataset
uspto-grants-1996_09
Patent number
US05559145

Reaction notes

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