Isopropyl chloroformate → Methylenechloride Hexane

HRID 744698Notes

Reaction equation

HRID 744698 reaction equation
[Cl:1][C:2](OC(C)C)=O.F[C:9]1[CH:17]=[CH:16][CH:15]=[CH:14][C:10]=1C([Cl:13])=O>>[CH3:16][CH2:17][CH2:9][CH2:10][CH2:14][CH3:15].[Cl:13][CH2:2][Cl:1]

Participants

3

Reactant 2

HCID 7917Isopropyl chloroformateHCID 98082-Fluorobenzoyl chloride

Product 1

HCID 21226440Methylenechloride HexaneYield 81%

Procedure

This compound was prepared according to the method described in Example 7, except that isopropyl chloroformate was replaced by an equivalent portion of o-fluorobenzoyl chloride and the reaction product was purified by recrystallization from a mixture of hexane/dichloromethane as colourless crystals mp 113.5°-114° C., yield 81%.

Workup

  1. customThis compound was prepared

Sources & evidence

ORD record
ord-efb98f5da6b5460b8e082c46d6aa1632
Source dataset
uspto-grants-1996_09
Patent number
US05559145

Reaction notes

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