Water → (2S,3S)-2-[Cbz(methyl)amino]-3-methylpentanal

HRID 74716Notes

Reaction equation

HRID 74716 reaction equation
[CH2:1]([O:8][C:9](=[O:19])[N:10]([C@@H:12]([C@@H:15]([CH3:18])[CH2:16][CH3:17])[CH2:13][OH:14])[CH3:11])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(N(CC)CC)C.O.COC(C)(C)C>CS(C)=O>[CH3:11][N:10]([C@@H:12]([C@@H:15]([CH3:18])[CH2:16][CH3:17])[CH:13]=[O:14])[C:9](=[O:19])[O:8][CH2:1][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

6

Conditions

Temperature
0 °C

Procedure

To a solution of #1 (8.27 g, 31.2 mmol, 1 eq.) in dimethyl sulfoxide (41.35 mL, 0.75 M), was added triethylamine (8.70 mL, 64.0 mmol, 2.05 eq.) and the mixture was cooled to 0° C. Sulfur trioxide pyridine complex (10.18 g, 63.96 mmol, 2.05 eq.) was then added portion-wise, while keeping the internal temperature below 8° C. The reaction was allowed to reach room temperature and was stirred for 18 hours. The reaction was poured into water (100 mL) and tert-butyl methyl ether (100 mL). The aqueous layer was back-extracted with tert-butyl methyl ether (50 mL) and the combined organic layers were washed with brine (100 mL), dried over magnesium sulfate, filtered, concentrated in vacuo and purified by silica gel chromatography (Gradient: 10% to 60% ethyl acetate in heptane) to provide #2 (7.14 g, 87%) as a colorless oil. 1H NMR (400 MHz, DMSO-d6), presumed to be a mixture of rotamers, characteristic signals: δ 9.61 (s, 1H), 7.26-7.42 (m, 5H), 5.01-5.13 (m, 2H), 4.04-4.12 (m, 1H), 2.86 and 2.82 (2 s, total 3H), 1.94-2.11 (br m, 1H), 1.26-1.42 (br m, 1H).

Workup

  1. additionSulfur trioxide pyridine complex (10.18 g, 63.96 mmol, 2.05 eq.) was then added portion-wise
  2. customthe internal temperature below 8° C
  3. customto reach room temperature
  4. extractionThe aqueous layer was back-extracted with tert-butyl methyl ether (50 mL)
  5. washthe combined organic layers were washed with brine (100 mL)
  6. dry with materialdried over magnesium sulfate
  7. filtrationfiltered
  8. concentrationconcentrated in vacuo
  9. custompurified by silica gel chromatography (Gradient: 10% to 60% ethyl acetate in heptane)

Sources & evidence

ORD record
ord-333b239e60d947ca9d346a6a12d1bc1f
Source dataset
uspto-grants-2014_09
Patent number
US08828401B2

Reaction notes

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