Hydrogen Peroxide → HCID 178484692, compound

HRID 750558Notes

Reaction equation

HRID 750558 reaction equation
[C:1]([C:3]([C:12]#[N:13])=[C:4]([NH:6][C:7](=[O:11])[N:8]([CH3:10])[CH3:9])[SH:5])#[N:2].[OH:14]O>O>[C:1]([C:3]1[C:12]([OH:14])=[N:13][S:5][C:4]=1[NH:6][C:7](=[O:11])[N:8]([CH3:10])[CH3:9])#[N:2]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 18549906HCID 18549906, compound

Product 1

HCID 178484692HCID 178484692, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

A solution of 3-(2,2-Dicyano-1-mercapto-vinyl)-1,1-dimethyl-urea (sodium salt) (30 g, 137 mmol) in water (300 mL) was treated at ambient temperature with hydrogen peroxide (14 mL of a 10 M solution). The reaction warmed and thickened with solid formation and so was treated with additional water (100 mL). The mixture was heated to reflux for 15 minutes, effecting complete dissolution and then cooled to ambient temperature. After 1 hour at ambient temperature, the mixture was concentrated to a constant weight (35 g, >100% due to water content) and was used immediately in the next step.

Workup

  1. temperatureThe reaction warmed
  2. temperatureThe mixture was heated
  3. temperatureto reflux for 15 minutes
  4. dissolutiondissolution
  5. concentrationthe mixture was concentrated to a constant weight (35 g, >100% due to water content)

Sources & evidence

ORD record
ord-cd5a72c91bc149c0b7bc9809fe2bc3e8
Source dataset
uspto-grants-2008_07
Patent number
US07405218B2

Reaction notes

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