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HRID78680

反应详情

EQUATION

反应方程式

HRID 78680 的结构方程式

REACTANTS

反应物

5
结构：N
HCID222

Ammonia gas

H3N

结构：O=S(=O)(O)O
HCID1118

Sulfuric acid

H2O4S

2 次

结构：ON=C1CCCCC1
HCID7517

Cyclohexanone oxime

C6H11NO

结构：O=S(=O)(O)O.O=S(=O)=O
HCID24681

未命名化合物

结构：O=C1CCCCCN1.O=S(=O)(O)O
HCID67062907

Sulfuric acid--azepan-2-one (1/1)

C6H13NO5S

PRODUCTS

生成物

2
结构：O=C1CCCCCN1
HCID7768

Caprolactam

C6H11NO

结构：O=S(=O)([O-])[O-].[NH4+].[NH4+]
HCID6097028

Ammonium sulfate

H8N2O4S

PROCEDURE

实验过程

The Beckmann rearrangement of the cyclohexanone oxime is carried out with sulfuric acid or oleum. The caprolactam sulfate prepared in this case and excess sulfuric acid are reacted with ammonia to give caprolactam and ammonium sulfate.