Chloride → 5-Hydroxy-1-benzothiophene-4-carbaldehyde

HRID 800594Notes

Reaction equation

HRID 800594 reaction equation
[CH2:16]([Cl:17])[Cl:18].[CH3:11][O:12][CH:13]([Cl:14])[Cl:15].[Cl-:19].[Cl-:20].[Cl-:21].[Cl-:22].[OH:1][c:2]1[cH:3][c:4]2[c:5]([s:6][cH:7][cH:8]2)[cH:9][cH:10]1.[Ti+4:23]>>[OH:1][c:2]1[c:3]([CH:11]=[O:12])[c:4]2[c:5]([s:6][cH:7][cH:8]2)[cH:9][cH:10]1

Participants

6

Reactant 5

HCID 312Chloride4×HCID 6344DichloromethaneHCID 21004Methane, dichloromethoxy-HCID 114942Titanium cation (4+)HCID 12203499Benzo[b]thiophen-5-ol

Product 1

HCID 134528765-Hydroxy-1-benzothiophene-4-carbaldehyde

Sources & evidence

ORD record
ord-824b0855ad494456b35009ebf235b0c5
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

Loading…