HRID800846

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID175

Acetate

C2H3O2-

2 次

HCID813

Potassium cation

K+

2 次

HCID11776

Triphenylphosphine

C18H15P

HCID19660

Carbonate

CO3-2

HCID31275

1,4-Dioxane

C4H8O2

HCID105144

Palladium(2+)

Pd+2

HCID44203102

3-Bromo-2-fluorobenzamide

C7H5BrFNO

HCID57813382

B-[3-[[[(1,1-Dimethylethyl)dimethylsilyl]oxy]methyl]phenyl]boronic acid

C13H23BO3Si

PRODUCTS

生成物

结构：CC(C)(C)[Si](C)(C)OCc1cccc(-c2cccc(C(N)=O)c2F)c1

HCID57813305

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-524d18c754044a91965d90b49e90b9fc
来源数据集: Test data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Test data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[Br:26][c:27]1[c:28]([F:36])[c:29]([C:30](=[O:31])[NH2:32])[cH:33][cH:34][cH:35]1.[CH2:55]1[O:56][CH2:57][CH2:58][O:59][CH2:60]1.[CH3:37][C:38]([CH3:39])([CH3:40])[Si:41]([O:42][CH2:43][c:44]1[cH:45][c:46]([B:50]([OH:51])[OH:52])[cH:47][cH:48][cH:49]1)([CH3:53])[CH3:54].[K+:20].[K+:21].[O-:22][C:23]([O-:24])=[O:25].[O-:62][C:63]([CH3:64])=[O:65].[O-:66][C:67]([CH3:68])=[O:69].[Pd+2:61].[c:1]1([P:2]([c:3]2[cH:4][cH:5][cH:6][cH:7][cH:8]2)[c:9]2[cH:10][cH:11][cH:12][cH:13][cH:14]2)[cH:15][cH:16][cH:17][cH:18][cH:19]1>>[c:27]1(-[c:46]2[cH:45][c:44]([CH2:43][O:42][Si:41]([C:38]([CH3:37])([CH3:39])[CH3:40])([CH3:53])[CH3:54])[cH:49][cH:48][cH:47]2)[c:28]([F:36])[c:29]([C:30](=[O:31])[NH2:32])[cH:33][cH:34][cH:35]1