Pyrrolidone carboxylic acid → tert-Butyl 5-oxo-DL-prolinate

HRID 801346Notes

Reaction equation

HRID 801346 reaction equation
[C:15](=[O:16])([OH:17])[O-:18].[C:20]([O:21][C:24]([CH3:25])([CH3:26])[CH3:27])(=[O:22])[CH3:23].[Cl+3:10]([OH:11])([O-:12])([O-:13])[O-:14].[NH:1]1[CH:2]([C:7](=[O:8])[OH:9])[CH2:3][CH2:4][C:5]1=[O:6].[Na+:19]>>[NH:1]1[CH:2]([C:7](=[O:8])[O:9][C:24]([CH3:25])([CH3:26])[CH3:27])[CH2:3][CH2:4][C:5]1=[O:6]

Participants

6

Reactant 5

HCID 499Pyrrolidone carboxylic acidHCID 769Bicarbonate IonHCID 923Sodium ionHCID 10908tert-Butyl acetateHCID 24247Perchloric Acid

Product 1

HCID 13295412tert-Butyl 5-oxo-DL-prolinate

Sources & evidence

ORD record
ord-8e2935f1d0204c1c98cd15edb4342384
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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