Sodium ion → 1-Piperazinecarboxylic acid, 4-(3-hydroxy-2-nitrophenyl)-, 1,1-dimethylethyl ester

HRID 801427Notes

Reaction equation

HRID 801427 reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[N:8]1[CH2:9][CH2:10][N:11]([c:14]2[c:15]([N+:21](=[O:22])[O-:23])[c:16]([F:20])[cH:17][cH:18][cH:19]2)[CH2:12][CH2:13]1.[CH3:24][S:25](=[O:26])([CH2:27][CH2:28][OH:29])=[O:30].[H-:31].[Na+:32].[O:33]=[CH:34][N:35]([CH3:36])[CH3:37]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[N:8]1[CH2:9][CH2:10][N:11]([c:14]2[c:15]([N+:21](=[O:22])[O-:23])[c:16]([OH:26])[cH:17][cH:18][cH:19]2)[CH2:12][CH2:13]1

Participants

6

Reactant 5

HCID 923Sodium ionHCID 6228DimethylformamideHCID 848342-(Methylsulfonyl)ethanolHCID 166653HydrideHCID 53255497tert-Butyl 4-(3-fluoro-2-nitrophenyl)piperazine-1-carboxylate

Product 1

HCID 576783021-Piperazinecarboxylic acid, 4-(3-hydroxy-2-nitrophenyl)-, 1,1-dimethylethyl ester

Sources & evidence

ORD record
ord-a305f3efb9984325bb3c5d8ee54eec0a
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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