Ammonia → 6-Iodo-4-methylquinolin-2(1H)-one

HRID 802561Notes

Reaction equation

HRID 802561 reaction equation
[Br:1][c:2]1[cH:3][c:4]2[c:5]([CH3:13])[cH:6][c:7](=[O:12])[nH:8][c:9]2[cH:10][cH:11]1.[CH2:23]1[O:24][CH2:25][CH2:26][O:27][CH2:28]1.[CH3:16][NH:17][CH2:18][CH2:19][NH:20][CH3:21].[Cu:29][I:30].[I-:14].[NH3:22].[Na+:15].[OH2:31]>>[c:2]1([I:14])[cH:3][c:4]2[c:5]([CH3:13])[cH:6][c:7](=[O:12])[nH:8][c:9]2[cH:10][cH:11]1

Participants

9

Reactant 8

HCID 222AmmoniaHCID 923Sodium ionHCID 962WaterHCID 8070N,N'-DimethylethylenediamineHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 30165Iodide IonHCID 312751,4-DioxaneHCID 63244626-Bromo-4-methylquinolin-2-ol

Product 1

HCID 126863636-Iodo-4-methylquinolin-2(1H)-one

Sources & evidence

ORD record
ord-0cf8cf9019854ee4aee18d5be3b0cf1f
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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