Bicarbonate Ion → (3-Amino-4-benzyloxy-phenoxy)-acetonitrile

HRID 802577Notes

Reaction equation

HRID 802577 reaction equation
[C:27](=[O:28])([OH:29])[O-:30].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[c:10]([N+:19]([O-:20])=[O:21])[cH:11][c:12]([O:13][CH2:14][C:15]#[N:16])[cH:17][cH:18]1.[CH3:32][CH2:33][O:34][C:35](=[O:36])[CH3:37].[Na+:31].[OH2:22].[OH2:23].[Sn:24]([Cl:25])[Cl:26]>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[O:8][c:9]1[c:10]([NH2:19])[cH:11][c:12]([O:13][CH2:14][C:15]#[N:16])[cH:17][cH:18]1

Participants

7

Reactant 6

HCID 769Bicarbonate IonHCID 923Sodium ionHCID 962Water2×HCID 8857Ethyl AcetateHCID 24479Stannous ChlorideHCID 18789746(4-Benzyloxy-3-nitro-phenoxy)-acetonitrile

Product 1

HCID 18789661(3-Amino-4-benzyloxy-phenoxy)-acetonitrile

Sources & evidence

ORD record
ord-b6c58b9728be4a6eafdabdcb640d5c49
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

Loading…