Potassium Cation → 2-(5-Methoxy-2-nitrophenyl)-1,3-dioxolane

HRID 802674Notes

Reaction equation

HRID 802674 reaction equation
[CH2:26]([Cl:27])[Cl:28].[CH3:14][Si:15]([O:16][CH2:17][CH2:18][O:21][Si:22]([CH3:23])([CH3:24])[CH3:25])([CH3:19])[CH3:20].[CH3:1][O:2][c:3]1[cH:4][cH:5][c:6]([N+:11](=[O:12])[O-:13])[c:7]([CH:8]=[O:9])[cH:10]1.[F:29][C:30]([F:31])([F:32])[S:33]([O:34][Si:35]([CH3:36])([CH3:37])[CH3:38])(=[O:39])=[O:40].[K+:41].[K+:42].[O-:43][C:44]([O-:45])=[O:46]>>[CH3:1][O:2][c:3]1[cH:4][cH:5][c:6]([N+:11](=[O:12])[O-:13])[c:7]([CH:8]2[O:9][CH2:18][CH2:17][O:16]2)[cH:10]1

Participants

7

Reactant 6

HCID 813Potassium Cation2×HCID 6344DichloromethaneHCID 19660Carbonate IonHCID 65367Trimethylsilyl triflateHCID 818582,2,7,7-Tetramethyl-3,6-dioxa-2,7-disilaoctaneHCID 2303715-Methoxy-2-nitrobenzaldehyde

Product 1

HCID 572490272-(5-Methoxy-2-nitrophenyl)-1,3-dioxolane

Sources & evidence

ORD record
ord-9edaccc00e984a3eabefae068b053737
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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