Acetate → Benzophenone (6-chloropyrimidin-4-yl)hydrazone

HRID 803751Notes

Reaction equation

HRID 803751 reaction equation
[C:9]([c:10]1[cH:11][cH:12][cH:13][cH:14][cH:15]1)([c:16]1[cH:17][cH:18][cH:19][cH:20][cH:21]1)=[N:22][NH2:23].[CH3:24][C:25]([CH3:26])([O-:27])[CH3:28].[Cl:1][c:2]1[n:3][cH:4][n:5][c:6]([Cl:8])[cH:7]1.[Na+:29].[O-:40][C:41]([CH3:42])=[O:43].[O-:44][C:45]([CH3:46])=[O:47].[OH:30][B:31]([c:32]1[cH:33][cH:34][cH:35][cH:36][cH:37]1)[OH:38].[Pd+2:39]>>[c:2]1([NH:23][N:22]=[C:9]([c:10]2[cH:11][cH:12][cH:13][cH:14][cH:15]2)[c:16]2[cH:17][cH:18][cH:19][cH:20][cH:21]2)[n:3][cH:4][n:5][c:6]([Cl:8])[cH:7]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 923Sodium ionHCID 66827Phenylboronic AcidHCID 709434,6-DichloropyrimidineHCID 79304DiphenylmethylidenehydrazineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 45749132-Methylpropan-2-olate

Product 1

HCID 86672326Benzophenone (6-chloropyrimidin-4-yl)hydrazone

Sources & evidence

ORD record
ord-383a95f2b0d840d0a118d0c3b3ab7018
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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