Bicarbonate Ion → Methanesulfonic acid 6-benzyloxy-2-bromo-naphthalen-1-yl ester

HRID 804162Notes

Reaction equation

HRID 804162 reaction equation
[C:28](=[O:29])([OH:30])[O-:31].[CH2:33]1[O:34][CH2:35][CH2:36][CH2:37]1.[CH2:3]([c:4]1[cH:5][cH:6][cH:7][cH:8][cH:9]1)[O:10][c:11]1[cH:12][c:13]2[cH:14][cH:15][c:16]([Br:22])[c:17]([OH:21])[c:18]2[cH:19][cH:20]1.[CH3:23][S:24]([Cl:25])(=[O:26])=[O:27].[H-:1].[Na+:2].[Na+:32].[OH2:38]>>[CH2:3]([c:4]1[cH:5][cH:6][cH:7][cH:8][cH:9]1)[O:10][c:11]1[cH:12][c:13]2[cH:14][cH:15][c:16]([Br:22])[c:17]([O:21][S:24]([CH3:23])(=[O:26])=[O:27])[c:18]2[cH:19][cH:20]1

Participants

8

Reactant 7

HCID 769Bicarbonate IonHCID 923Sodium ion2×HCID 962WaterHCID 8028TetrahydrofuranHCID 31297Methanesulfonyl chlorideHCID 166653HydrideHCID 670051586-Benzyloxy-2-bromo-naphthalen-1-ol

Product 1

HCID 86626526Methanesulfonic acid 6-benzyloxy-2-bromo-naphthalen-1-yl ester

Sources & evidence

ORD record
ord-658e28181f6b4515a3b81cee32a0aff4
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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