Bromide ion → 3-Cyano-2-(4-nitrophenylthio)-5-[2-(4-ethoxycarbonylphenyl)ethenyl]pyridine

HRID 804406Notes

Reaction equation

HRID 804406 reaction equation
[Br-:1].[C:2](#[N:3])[c:4]1[c:5]([S:30][c:31]2[cH:32][cH:33][c:34]([N+:37](=[O:38])[O-:39])[cH:35][cH:36]2)[n:6][cH:7][c:8]([CH2:10][P+:11]([c:12]2[cH:13][cH:14][cH:15][cH:16][cH:17]2)([c:18]2[cH:19][cH:20][cH:21][cH:22][cH:23]2)[c:24]2[cH:25][cH:26][cH:27][cH:28][cH:29]2)[cH:9]1.[CH2:51]([CH3:52])[O:53][C:54](=[O:55])[c:56]1[cH:57][cH:58][c:59]([CH:60]=[O:61])[cH:62][cH:63]1.[CH3:40][CH2:41][N:42]([CH2:43][CH3:44])[CH2:45][CH3:46].[CH:47]([Cl:48])([Cl:49])[Cl:50].[OH2:64]>>[C:2](#[N:3])[c:4]1[c:5]([S:30][c:31]2[cH:32][cH:33][c:34]([N+:37](=[O:38])[O-:39])[cH:35][cH:36]2)[n:6][cH:7][c:8]([CH:10]=[CH:60][c:59]2[cH:58][cH:57][c:56]([C:54]([O:53][CH2:51][CH3:52])=[O:55])[cH:63][cH:62]2)[cH:9]1

Participants

7

Reactant 6

HCID 259Bromide ionHCID 962WaterHCID 6212ChloroformHCID 8471TriethylamineHCID 80498Ethyl 4-formylbenzoateHCID 19754089[5-Cyano-6-(4-nitrophenyl)sulfanyl-3-pyridinyl]methyl-triphenylphosphanium

Product 1

HCID 542227863-Cyano-2-(4-nitrophenylthio)-5-[2-(4-ethoxycarbonylphenyl)ethenyl]pyridine

Sources & evidence

ORD record
ord-686ff1496801446eb0cc76ae9b2217e7
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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