Chloride → (4-Bromo-2-trifluoromethoxy-phenyl)-acetaldehyde

HRID 804702Notes

Reaction equation

HRID 804702 reaction equation
[Br:37][c:38]1[cH:39][c:40]([O:46][C:47]([F:48])([F:49])[F:50])[c:41]([CH:42]=[O:43])[cH:44][cH:45]1.[CH2:31]1[CH2:32][CH2:33][CH2:34][CH2:35][CH2:36]1.[CH3:2][O:3][CH2:4][P+:5]([c:6]1[cH:7][cH:8][cH:9][cH:10][cH:11]1)([c:12]1[cH:13][cH:14][cH:15][cH:16][cH:17]1)[c:18]1[cH:19][cH:20][cH:21][cH:22][cH:23]1.[CH3:51][CH2:52][O:53][CH2:54][CH3:55].[Cl-:1].[c:24]1([Li:25])[cH:26][cH:27][cH:28][cH:29][cH:30]1>>[CH:2](=[O:3])[CH2:42][c:41]1[c:40]([O:46][C:47]([F:48])([F:49])[F:50])[cH:39][c:38]([Br:37])[cH:45][cH:44]1

Participants

7

Reactant 6

HCID 312ChlorideHCID 3283Diethyl EtherHCID 8078CyclohexaneHCID 2723799(Methoxymethyl)triphenylphosphonium chlorideHCID 187000874-Bromo-2-(trifluoromethoxy)benzaldehydeHCID 178506676HCID 178506676, compound

Product 1

HCID 86600516(4-Bromo-2-trifluoromethoxy-phenyl)-acetaldehyde

Sources & evidence

ORD record
ord-81705075be10444da2ba230779c22dac
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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