Acetate → 4-(4-chlorophenyl)-1-methyl-1H-pyrazole-5-carbaldehyde
Reaction equation
[Br-:26].[Br:1][c:2]1[cH:3][n:4][n:5]([CH3:9])[c:6]1[CH:7]=[O:8].[C:20](=[O:21])([O-:22])[O-:23].[C:51]([O-:52])(=[O:53])[CH3:54].[C:56]([O-:57])(=[O:58])[CH3:59].[CH3:27][CH2:28][CH2:29][CH2:30][N+:31]([CH2:32][CH2:33][CH2:34][CH3:35])([CH2:36][CH2:37][CH2:38][CH3:39])[CH2:40][CH2:41][CH2:42][CH3:43].[CH3:45][CH2:46][O:47][C:48](=[O:49])[CH3:50].[Cl:10][c:11]1[cH:12][cH:13][c:14]([B:17]([OH:18])[OH:19])[cH:15][cH:16]1.[K+:24].[K+:25].[OH2:44].[Pd+2:55]>>[c:2]1(-[c:14]2[cH:13][cH:12][c:11]([Cl:10])[cH:16][cH:15]2)[cH:3][n:4][n:5]([CH3:9])[c:6]1[CH:7]=[O:8]Participants
11
Reactant 10
HCID 175Acetate2×
HCID 259Bromide ion
HCID 813Potassium Cation2×
HCID 962Water
HCID 8857Ethyl Acetate
HCID 16028Tetrabutylammonium
HCID 19660Carbonate Ion
HCID 742994-Chlorophenylboronic acid
HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)
HCID 27946344-bromo-1-methyl-1H-pyrazole-5-carbaldehydeProduct 1
Sources & evidence
- ORD record
- ord-739692c93b21453094abea20f60c9dfa
- Source dataset
- Test data from https://doi.org/10.1039/C8SC04228D
Reaction notes
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