Acetone → Dimethyl 5-bentyloxy-isophthalate

HRID 806128Notes

Reaction equation

HRID 806128 reaction equation
[Br:7][CH2:8][c:9]1[cH:10][cH:11][cH:12][cH:13][cH:14]1.[CH3:15][O:16][C:17]([c:18]1[cH:19][c:20]([C:21](=[O:22])[O:23][CH3:24])[cH:25][c:26]([OH:28])[cH:27]1)=[O:29].[CH3:30][C:31](=[O:32])[CH3:33].[K+:1].[K+:2].[O-:3][C:4]([O-:5])=[O:6]>>[CH2:8]([c:9]1[cH:10][cH:11][cH:12][cH:13][cH:14]1)[O:28][c:26]1[cH:25][c:20]([C:21](=[O:22])[O:23][CH3:24])[cH:19][c:18]([C:17]([O:16][CH3:15])=[O:29])[cH:27]1

Participants

6

Reactant 5

HCID 180AcetoneHCID 813Potassium Cation2×HCID 7498Benzyl BromideHCID 19660Carbonate IonHCID 830651,3-Benzenedicarboxylic acid, 5-hydroxy-, 1,3-dimethyl ester

Product 1

HCID 7643390Dimethyl 5-bentyloxy-isophthalate

Sources & evidence

ORD record
ord-9a67b29a7e1b422cb8340ec4188ae089
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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