Tetrahydrofuran → N-[1-(4-bromo-2-methylphenyl)ethylidene]-2-methylpropane-2-sulfinamide

HRID 807213Notes

Reaction equation

HRID 807213 reaction equation
[Br:1][c:2]1[cH:3][c:4]([CH3:11])[c:5]([C:8]([CH3:9])=[O:10])[cH:6][cH:7]1.[CH3:12][C:13]([CH3:14])([CH3:15])[S:16](=[O:17])[NH2:18].[CH3:24][CH2:25][O-:26].[CH3:28][CH2:29][O-:30].[CH3:31][CH2:32][O-:33].[CH3:34][CH2:35][O-:36].[O:19]1[CH2:20][CH2:21][CH2:22][CH2:23]1.[Ti+4:27]>>[Br:1][c:2]1[cH:3][c:4]([CH3:11])[c:5]([C:8]([CH3:9])=[N:18][S:16]([C:13]([CH3:12])([CH3:14])[CH3:15])=[O:17])[cH:6][cH:7]1

Participants

6

Reactant 5

HCID 8028TetrahydrofuranHCID 114942Titanium cation (4+)HCID 1194401-Hydroxyethyl radical4×HCID 3382465Tert-ButanesulfinamideHCID 219385361-(4-Bromo-2-methylphenyl)ethan-1-one

Product 1

HCID 76656334N-[1-(4-bromo-2-methylphenyl)ethylidene]-2-methylpropane-2-sulfinamide

Sources & evidence

ORD record
ord-e4876e4ad14041219eca23b2fa8b06b0
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

Loading…