Sodium ion → 1,3-Diethyl 2-(4-bromophenyl)-2-methylpropanedioate

HRID 807872Notes

Reaction equation

HRID 807872 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([CH:8]([C:9](=[O:10])[O:11][CH2:12][CH3:13])[C:14](=[O:15])[O:16][CH2:17][CH3:18])[cH:6][cH:7]1.[CH2:23]1[O:24][CH2:25][CH2:26][CH2:27]1.[H-:19].[I:21][CH3:22].[Na+:20]>>[Br:1][c:2]1[cH:3][cH:4][c:5]([C:8]([C:9](=[O:10])[O:11][CH2:12][CH3:13])([C:14](=[O:15])[O:16][CH2:17][CH3:18])[CH3:22])[cH:6][cH:7]1

Participants

6

Reactant 5

HCID 923Sodium ionHCID 6328Methyl iodideHCID 8028TetrahydrofuranHCID 166653HydrideHCID 10519382Diethyl 4-bromophenylmalonate

Product 1

HCID 106163071,3-Diethyl 2-(4-bromophenyl)-2-methylpropanedioate

Sources & evidence

ORD record
ord-86d96ac316944320a868f9129f9badd0
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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