Acetate → 4'-Nitro[1,1'-biphenyl]-3-carbaldehyde

HRID 808475Notes

Reaction equation

HRID 808475 reaction equation
[Br:1][c:2]1[cH:3][c:4]([CH:5]=[O:6])[cH:7][cH:8][cH:9]1.[C:10](=[O:11])([O-:12])[O-:13].[N+:16](=[O:17])([O-:18])[c:19]1[cH:20][cH:21][c:22]([B:25]([OH:26])[OH:27])[cH:23][cH:24]1.[Na+:14].[Na+:15].[O-:35][C:36]([CH3:37])=[O:38].[O-:39][C:40]([CH3:41])=[O:42].[O:28]=[CH:29][N:30]([CH3:31])[CH3:32].[OH2:33].[Pd+2:34]>>[c:2]1(-[c:22]2[cH:21][cH:20][c:19]([N+:16](=[O:17])[O-:18])[cH:24][cH:23]2)[cH:3][c:4]([CH:5]=[O:6])[cH:7][cH:8][cH:9]1

Participants

9

Reactant 8

HCID 175Acetate2×HCID 923Sodium ion2×HCID 962WaterHCID 6228DimethylformamideHCID 19660Carbonate IonHCID 765833-BromobenzaldehydeHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 27735524-Nitrophenylboronic acid

Product 1

HCID 461934594'-Nitro[1,1'-biphenyl]-3-carbaldehyde

Sources & evidence

ORD record
ord-6542867299e7473d92cac1d92b60a757
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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