Potassium Cation → Methyl 2,6-dimethoxybiphenyl-4-carboxylate

HRID 809590Notes

Reaction equation

HRID 809590 reaction equation
[Br:1][c:2]1[c:3]([O:14][CH3:15])[cH:4][c:5]([C:6](=[O:7])[O:8][CH3:9])[cH:10][c:11]1[O:12][CH3:13].[CH3:33][C:34]#[N:35].[K+:30].[K+:31].[K+:32].[OH:16][B:17]([OH:18])[c:19]1[cH:20][cH:21][cH:22][cH:23][cH:24]1.[P:25]([O-:26])([O-:27])([O-:28])=[O:29]>>[c:2]1(-[c:19]2[cH:20][cH:21][cH:22][cH:23][cH:24]2)[c:3]([O:14][CH3:15])[cH:4][c:5]([C:6](=[O:7])[O:8][CH3:9])[cH:10][c:11]1[O:12][CH3:13]

Participants

6

Reactant 5

HCID 813Potassium Cation3×HCID 1061PhosphateHCID 6342AcetonitrileHCID 66827Phenylboronic AcidHCID 117713Methyl 4-bromo-3,5-dimethoxybenzoate

Product 1

HCID 57930909Methyl 2,6-dimethoxybiphenyl-4-carboxylate

Sources & evidence

ORD record
ord-e1615d07bce94072a967b5a72ead2ebe
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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