Hydrochloric Acid → Dimethyl (4-methoxy-2-nitrobenzyl)malonate

HRID 817992Notes

Reaction equation

HRID 817992 reaction equation
[BH4-:22].[CH3:1][O:2][c:3]1[cH:4][c:5]([N+:19](=[O:20])[O-:21])[c:6]([CH:9]=[C:10]([C:11](=[O:12])[O:13][CH3:14])[C:15](=[O:16])[O:17][CH3:18])[cH:7][cH:8]1.[CH3:25][OH:26].[ClH:24].[Na+:23]>>[CH3:1][O:2][c:3]1[cH:4][c:5]([N+:19](=[O:20])[O-:21])[c:6]([CH2:9][CH:10]([C:11](=[O:12])[O:13][CH3:14])[C:15](=[O:16])[O:17][CH3:18])[cH:7][cH:8]1

Participants

6

Reactant 5

HCID 313Hydrochloric AcidHCID 887MethanolHCID 923Sodium ionHCID 28123BorohydrideHCID 54325413Dimethyl (4-methoxy-2-nitrophenyl)methylidenemalonate

Product 1

HCID 53955072Dimethyl (4-methoxy-2-nitrobenzyl)malonate

Sources & evidence

ORD record
ord-cf35aaf6acbb4b338c65fb49a5440a53
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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