Dimethyl Sulfoxide → Methyl 4-(benzyloxy)-3-bromobenzoate

HRID 818422Notes

Reaction equation

HRID 818422 reaction equation
[Br:13][CH2:14][c:15]1[cH:16][cH:17][cH:18][cH:19][cH:20]1.[Br:1][c:2]1[cH:3][c:4]([C:5](=[O:6])[O:7][CH3:8])[cH:9][cH:10][c:11]1[OH:12].[C:21](=[O:22])([O-:23])[O-:24].[CH3:27][S:28]([CH3:29])=[O:30].[Cs+:25].[Cs+:26].[OH2:31]>>[Br:1][c:2]1[cH:3][c:4]([C:5](=[O:6])[O:7][CH3:8])[cH:9][cH:10][c:11]1[O:12][CH2:14][c:15]1[cH:16][cH:17][cH:18][cH:19][cH:20]1

Participants

7

Reactant 6

HCID 679Dimethyl SulfoxideHCID 962WaterHCID 7498Benzyl BromideHCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 4778958Methyl 3-bromo-4-hydroxybenzoate

Product 1

HCID 23111814Methyl 4-(benzyloxy)-3-bromobenzoate

Sources & evidence

ORD record
ord-74481084b16e46c09b598fbbea49bbd0
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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