Bromide ion → Methyl 4-(oxan-4-ylidenemethyl)benzoate

HRID 818977Notes

Reaction equation

HRID 818977 reaction equation
[Br-:3].[CH3:41][S:42]([CH3:43])=[O:44].[CH3:4][O:5][C:6](=[O:7])[c:8]1[cH:9][cH:10][c:11]([CH2:12][P+:13]([c:14]2[cH:15][cH:16][cH:17][cH:18][cH:19]2)([c:20]2[cH:21][cH:22][cH:23][cH:24][cH:25]2)[c:26]2[cH:27][cH:28][cH:29][cH:30][cH:31]2)[cH:32][cH:33]1.[H-:1].[Na+:2].[O:34]1[CH2:35][CH2:36][C:37](=[O:40])[CH2:38][CH2:39]1.[OH2:45]>>[CH3:4][O:5][C:6](=[O:7])[c:8]1[cH:9][cH:10][c:11]([CH:12]=[C:37]2[CH2:36][CH2:35][O:34][CH2:39][CH2:38]2)[cH:32][cH:33]1

Participants

8

Reactant 7

HCID 259Bromide ionHCID 679Dimethyl SulfoxideHCID 923Sodium ionHCID 962WaterHCID 121599Tetrahydro-4H-pyran-4-oneHCID 166653HydrideHCID 2764258(4-Methoxycarbonylphenyl)methyl-triphenylphosphanium

Product 1

HCID 67333428Methyl 4-(oxan-4-ylidenemethyl)benzoate

Sources & evidence

ORD record
ord-f81279d6331a4084bad44b8753395084
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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