Ethanol → 7-hydroxy-2,2-dimethyl-2H-chromene-3-carbaldehyde

HRID 819156Notes

Reaction equation

HRID 819156 reaction equation
[C:19]12([CH2:20][S:21]([OH:22])(=[O:23])=[O:24])[C:25]([CH3:26])([CH3:27])[CH:28]([CH2:29][CH2:30]1)[CH2:31][C:32]2=[O:33].[CH3:1][O:2][CH2:3][O:4][c:5]1[cH:6][cH:7][c:8]2[c:13]([cH:14]1)[O:12][C:11]([CH3:15])([CH3:16])[C:10]([CH:17]=[O:18])=[CH:9]2.[CH3:34][CH2:35][OH:36]>>[OH:4][c:5]1[cH:6][cH:7][c:8]2[c:13]([cH:14]1)[O:12][C:11]([CH3:15])([CH3:16])[C:10]([CH:17]=[O:18])=[CH:9]2

Participants

4

Reactant 3

HCID 702EthanolHCID 18462Bicyclo[2.2.1]heptane-1-methanesulfonic acid, 7,7-dimethyl-2-oxo-, (1S)-HCID 584386707-(methoxymethoxy)-2,2-dimethyl-2H-chromene-3-carbaldehyde

Product 1

HCID 584387357-hydroxy-2,2-dimethyl-2H-chromene-3-carbaldehyde

Sources & evidence

ORD record
ord-33f9564016eb4bb0b6e28f17ee5becf0
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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