Acetate → 2-[4-(2,8-diphenyldibenzothiophen-4-yl)phenyl]-1-phenyl-1H-benzimidazole
Reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5](-[c:8]2[n:9][c:10]3[c:11]([n:12]2-[c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[cH:19][cH:20][cH:21][cH:22]3)[cH:6][cH:7]1.[C:73](=[O:74])([O-:75])[O-:76].[CH3:88][CH2:89][OH:90].[CH3:91][c:92]1[cH:93][cH:94][cH:95][cH:96][cH:97]1.[K+:77].[K+:78].[O-:80][C:81]([CH3:82])=[O:83].[O-:84][C:85]([CH3:86])=[O:87].[Pd+2:79].[c:23]1(-[c:29]2[cH:30][c:31]3[c:32]([s:33][c:34]4[c:35]3[cH:36][c:37](-[c:40]3[cH:41][cH:42][cH:43][cH:44][cH:45]3)[cH:38][cH:39]4)[c:46]([B:48]([OH:49])[OH:50])[cH:47]2)[cH:24][cH:25][cH:26][cH:27][cH:28]1.[c:51]1([CH3:52])[cH:53][cH:54][cH:55][cH:56][c:57]1[P:58]([c:59]1[cH:60][cH:61][cH:62][cH:63][c:64]1[CH3:65])[c:66]1[cH:67][cH:68][cH:69][cH:70][c:71]1[CH3:72]>>[c:2]1(-[c:46]2[c:32]3[c:31]([cH:30][c:29](-[c:23]4[cH:24][cH:25][cH:26][cH:27][cH:28]4)[cH:47]2)[c:35]2[c:34]([s:33]3)[cH:39][cH:38][c:37](-[c:40]3[cH:41][cH:42][cH:43][cH:44][cH:45]3)[cH:36]2)[cH:3][cH:4][c:5](-[c:8]2[n:9][c:10]3[c:11]([n:12]2-[c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[cH:19][cH:20][cH:21][cH:22]3)[cH:6][cH:7]1Participants
10
Reactant 9
HCID 175Acetate2×
HCID 702Ethanol
HCID 813Potassium Cation2×
HCID 1140Toluene
HCID 19660Carbonate Ion
HCID 80271Tri-o-tolylphosphine
HCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)
HCID 230940702-(4-Bromophenyl)-1-phenyl-1H-benzo(d)imidazole
HCID 583096712,8-Diphenyldibenzothiophen-4-boronic acidProduct 1
Sources & evidence
- ORD record
- ord-8c1c706711e143c0a949ff36226ccd48
- Source dataset
- Test data from https://doi.org/10.1039/C8SC04228D
Reaction notes
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