Sodium ion → Methyl 5-iodo-1-benzothiophene-2-carboxylate

HRID 820301Notes

Reaction equation

HRID 820301 reaction equation
[Br:9][c:10]1[cH:11][c:12]2[c:13]([s:14][c:15]([C:17](=[O:18])[O:19][CH3:20])[cH:16]2)[cH:21][cH:22]1.[CH2:23]1[O:24][CH2:25][CH2:26][O:27][CH2:28]1.[CH3:3][NH:4][CH2:5][CH2:6][NH:7][CH3:8].[Cu:29][I:30].[I-:1].[Na+:2]>>[I:1][c:10]1[cH:11][c:12]2[c:13]([s:14][c:15]([C:17](=[O:18])[O:19][CH3:20])[cH:16]2)[cH:21][cH:22]1

Participants

7

Reactant 6

HCID 923Sodium ionHCID 8070N,N'-DimethylethylenediamineHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 30165Iodide IonHCID 312751,4-DioxaneHCID 2824065methyl 5-bromo-1-benzothiophene-2-carboxylate

Product 1

HCID 19007488Methyl 5-iodo-1-benzothiophene-2-carboxylate

Sources & evidence

ORD record
ord-629c9bf402ce47f7b2a983d266741cc2
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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