Dimethyl Sulfoxide → tert-butyl N-(4-methyl-1-oxopentan-2-yl)carbamate

HRID 821872Notes

Reaction equation

HRID 821872 reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[NH:8][CH:9]([CH2:10][OH:11])[CH2:12][CH:13]([CH3:14])[CH3:15].[CH3:16][CH2:17][N:18]([CH2:19][CH3:20])[CH2:21][CH3:22].[CH3:33][S:34]([CH3:35])=[O:36].[S:29](=[O:30])(=[O:31])=[O:32].[n:23]1[cH:24][cH:25][cH:26][cH:27][cH:28]1>>[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[NH:8][CH:9]([CH:10]=[O:11])[CH2:12][CH:13]([CH3:14])[CH3:15]

Participants

6

Reactant 5

HCID 679Dimethyl SulfoxideHCID 1049PyridineHCID 8471TriethylamineHCID 24682Sulfur trioxideHCID 546110tert-butyl N-(1-hydroxy-4-methylpentan-2-yl)carbamate

Product 1

HCID 546109tert-butyl N-(4-methyl-1-oxopentan-2-yl)carbamate

Sources & evidence

ORD record
ord-bba81dfe31c94f149bb92aeaab20c009
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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