HRID823551

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8028

Tetrahydrofuran

C4H8O

HCID12679

Hexamethylphosphoramide

C6H18N3OP

HCID30165

Iodide ion

I-

HCID735900

1-Boc-4-piperidone

C10H17NO3

结构：c1ccc(CCCC[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID18187516

未命名化合物

HCID178418339

Butyllithium

C4H9Li

PRODUCTS

生成物

结构：CC(C)(C)OC(=O)N1CCC(=CCCCc2ccccc2)CC1

HCID59371467

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-4ddffe7fae564eaebcf0cca7cf6e6066
来源数据集: Test data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Test data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[CH2:61]1[O:62][CH2:63][CH2:64][CH2:65]1.[CH3:31][N:32]([CH3:33])[P:34]([N:35]([CH3:36])[CH3:37])([N:38]([CH3:39])[CH3:40])=[O:41].[CH3:42][CH2:43][CH2:44][CH2:45][Li:46].[I-:1].[O:47]=[C:48]1[CH2:49][CH2:50][N:51]([C:54](=[O:55])[O:56][C:57]([CH3:58])([CH3:59])[CH3:60])[CH2:52][CH2:53]1.[c:2]1([P+:3]([c:4]2[cH:5][cH:6][cH:7][cH:8][cH:19]2)([CH2:9][CH2:10][CH2:11][CH2:12][c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[c:20]2[cH:21][cH:22][cH:23][cH:24][cH:25]2)[cH:26][cH:27][cH:28][cH:29][cH:30]1>>[CH:9]([CH2:10][CH2:11][CH2:12][c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1)=[C:48]1[CH2:49][CH2:50][N:51]([C:54](=[O:55])[O:56][C:57]([CH3:58])([CH3:59])[CH3:60])[CH2:52][CH2:53]1