Chloride → N,N-diethyl-7-phenyl-3,5-dihydroxy-6-heptenamide

HRID 823674Notes

Reaction equation

HRID 823674 reaction equation
[C:22]([BH3-:23])#[N:24].[CH2:1]([CH3:2])[N:3]([C:4]([CH2:5][C:6]([CH2:7][CH:8]([CH:9]=[CH:10][c:11]1[cH:12][cH:13][cH:14][cH:15][cH:16]1)[OH:17])=[O:18])=[O:19])[CH2:20][CH3:21].[CH3:26][CH:27]([CH3:28])[O-:29].[CH3:30][CH:31]([CH3:32])[O-:33].[CH3:34][CH:35]([CH3:36])[O-:37].[Cl-:38].[Na+:25].[Ti+4:39]>>[CH2:1]([CH3:2])[N:3]([C:4]([CH2:5][CH:6]([CH2:7][CH:8]([CH:9]=[CH:10][c:11]1[cH:12][cH:13][cH:14][cH:15][cH:16]1)[OH:17])[OH:18])=[O:19])[CH2:20][CH3:21]

Participants

7

Reactant 6

HCID 312ChlorideHCID 923Sodium ionHCID 114942Titanium cation (4+)HCID 498716Cyano-borohydrideHCID 3260420Isopropanolate3×HCID 54551573N,N-diethyl-7-phenyl-5-hydroxy-3-oxo-6-heptenamide

Product 1

HCID 54030271N,N-diethyl-7-phenyl-3,5-dihydroxy-6-heptenamide

Sources & evidence

ORD record
ord-8b5900e7b73440279ef619050abcf0bd
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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