Acetate → 1-Bromo-4-(2-phenylethenyl)benzene

HRID 824328Notes

Reaction equation

HRID 824328 reaction equation
[Br:1][c:2]1[cH:3][cH:4][c:5]([C:6]([Cl:7])=[O:8])[cH:9][cH:10]1.[C:40]([O-:41])(=[O:42])[CH3:43].[C:45]([O-:46])(=[O:47])[CH3:48].[CH2:11]=[CH:12][c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1.[CH2:19]([N:20]([CH2:21][CH2:22][CH2:23][CH3:24])[CH2:25][CH2:26][CH2:27][CH3:28])[CH2:29][CH2:30][CH3:31].[CH3:32][c:33]1[cH:34][cH:35][c:36]([CH3:37])[cH:38][cH:39]1.[Pd+2:44]>>[Br:1][c:2]1[cH:3][cH:4][c:5]([CH:6]=[CH:12][c:13]2[cH:14][cH:15][cH:16][cH:17][cH:18]2)[cH:9][cH:10]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 7501StyreneHCID 7622TributylamineHCID 7809P-XyleneHCID 685154-Bromobenzoyl chlorideHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 6013891-Bromo-4-(2-phenylethenyl)benzene

Sources & evidence

ORD record
ord-ae9e5010d5d64084880ad82cb997232a
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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