Potassium Cation → Tert-butyl 4-(4-amino-3-nitrophenoxy)picolinate

HRID 824754Notes

Reaction equation

HRID 824754 reaction equation
[C:36](=[O:37])([O-:38])[O-:39].[CH3:2][Si:3]([N-:4][Si:5]([CH3:6])([CH3:7])[CH3:8])([CH3:9])[CH3:10].[CH3:42][N:43]([CH3:44])[CH:45]=[O:46].[Cl:22][c:23]1[cH:24][c:25]([C:29](=[O:30])[O:31][C:32]([CH3:33])([CH3:34])[CH3:35])[n:26][cH:27][cH:28]1.[K+:1].[K+:40].[K+:41].[NH2:11][c:12]1[c:13]([N+:19](=[O:20])[O-:21])[cH:14][c:15]([OH:18])[cH:16][cH:17]1>>[NH2:11][c:12]1[c:13]([N+:19](=[O:20])[O-:21])[cH:14][c:15]([O:18][c:23]2[cH:24][c:25]([C:29](=[O:30])[O:31][C:32]([CH3:33])([CH3:34])[CH3:35])[n:26][cH:27][cH:28]2)[cH:16][cH:17]1

Participants

7

Reactant 6

HCID 813Potassium Cation3×HCID 6228DimethylformamideHCID 19660Carbonate IonHCID 3280088Npc316347HCID 37588824-Amino-3-NitrophenolHCID 11806045tert-Butyl 4-chloropicolinate

Product 1

HCID 22041090Tert-butyl 4-(4-amino-3-nitrophenoxy)picolinate

Sources & evidence

ORD record
ord-a4c8c6c261164e9093479836bb89f7cc
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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