Methanol → 2-Methoxy-2'-nitro-4,4'-dibromobiphenyl

HRID 824942Notes

Reaction equation

HRID 824942 reaction equation
[Br:6][c:7]1[cH:8][c:9]([N+:23]([O-:24])=[O:25])[c:10](-[c:13]2[c:14]([N+:20](=[O:21])[O-:22])[cH:15][c:16]([Br:19])[cH:17][cH:18]2)[cH:11][cH:12]1.[CH3:1][O-:2].[CH3:4][OH:5].[Na+:3].[O:26]=[CH:27][N:28]([CH3:29])[CH3:30]>>[CH3:1][O:2][c:9]1[cH:8][c:7]([Br:6])[cH:12][cH:11][c:10]1-[c:13]1[c:14]([N+:20](=[O:21])[O-:22])[cH:15][c:16]([Br:19])[cH:17][cH:18]1

Participants

6

Reactant 5

HCID 887MethanolHCID 923Sodium ionHCID 6228DimethylformamideHCID 3826051MethoxideHCID 100466484,4'-Dibromo-2,2'-dinitro-1,1'-biphenyl

Product 1

HCID 99774712-Methoxy-2'-nitro-4,4'-dibromobiphenyl

Sources & evidence

ORD record
ord-2246fcfab19f42c49c98eb9f575eda76
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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