Potassium Cation → 2-(2-Chloro-5-methoxy-phenyl)-propionaldehyde

HRID 825004Notes

Reaction equation

HRID 825004 reaction equation
[C:27]([CH:28]([CH:29]([C:30]([O-:31])=[O:32])[OH:33])[OH:34])([O-:35])=[O:36].[CH3:16][CH:17]([CH2:18][AlH:19][CH2:20][CH:21]([CH3:22])[CH3:23])[CH3:24].[CH3:1][O:2][C:3]([CH:4]([CH3:5])[c:6]1[c:7]([Cl:14])[cH:8][cH:9][c:10]([O:12][CH3:13])[cH:11]1)=[O:15].[CH3:25][OH:26].[CH3:39][c:40]1[cH:41][cH:42][cH:43][cH:44][cH:45]1.[K+:38].[Na+:37]>>[O:2]=[CH:3][CH:4]([CH3:5])[c:6]1[c:7]([Cl:14])[cH:8][cH:9][c:10]([O:12][CH3:13])[cH:11]1

Participants

8

Reactant 7

HCID 813Potassium CationHCID 887MethanolHCID 923Sodium ionHCID 1140TolueneHCID 14487Diisobutylaluminum hydrideHCID 38061142,3-DihydroxybutanedioateHCID 574213402-(2-Chloro-5-methoxy-phenyl)-propionic acid methyl ester

Product 1

HCID 574499712-(2-Chloro-5-methoxy-phenyl)-propionaldehyde

Sources & evidence

ORD record
ord-78f8caead29d4c6c96ecba16edd7626a
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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